Try creating an Excel report in the Dashboard module with this query
SELECT TS_TEST_ID, TS_NAME, TC_TEST_ID, TC_TESTCYCL_ID FROM TEST left JOIN TESTCYCL ON TESTCYCL.TC_TEST_ID = TEST.TS_TEST_ID order by testcycl.tc_test_id, test.ts_test_id asc
That will give you a list of all tests in the Test Plan, and each associated Test Instance in the Test Lab. If there is no associated Test Instance, then the TC_TEST_ID and TC_TESTCYCL_ID fields will be blank for those Tests.